4.7 Article

Two transition metal phosphonate photocatalysts for H2 evolution and CO2 reduction+

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 52, Pages 7195-7198

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc02822b

Keywords

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Funding

  1. National Natural Science Foundation of China [21333006, 21573135, 11374190, 51321091, 51602179]
  2. Taishan Scholar Foundation of Shandong Province, China
  3. [2016WLJH16]

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Two transition metal (Co and Ni) ion phosphonates as isostructural organic inorganic hybrids are prepared and investigated in terms of photocatalytic hydrogen evolution from water and CO2 reduction under UV light irradiation. A photocatalytic mechanism of ligand-to-metal charge transfer (LMCT) is proposed.

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