4.7 Article

Three-dimensional iron(II) porous coordination polymer exhibiting carbon dioxide-dependent spin crossover

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 34, Pages 4262-4265

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc00678d

Keywords

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Funding

  1. Basic Science Research Program [2013007314, 2015R1D1A1A01059872, 2017R1A2B4008757]
  2. National Research Foundation of Korea (NRF) [2012K2A2A4012500, 2016K2A9A2A08003735]
  3. MEST
  4. POSTECH

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We report a three-dimensional Fe(II) porous coordination polymer that exhibits a spin crossover temperature change following CO2 sorption (though not N-2 sorption). Furthermore, single crystals of the desolvated polymer with CO2 molecules at three different temperatures were characterised by X-ray crystallography.

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