Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 10, Pages 1233-1236Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08214b
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Funding
- EPSRC [EP/N011384/1]
- EPSRC (DTP award)
- EPSRC [EP/N011384/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [1687900, 1489071, EP/N011384/1] Funding Source: researchfish
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Cooperativity between the Li and Al centres is implicated in catalytic hydroboration reactions of aldehydes and ketones with pinacolborane via heteroleptic lithium diamidodihydridoaluminates. In addition to implementing hydroalumination, these versatile heteroleptic ates can also perform as amido bases as illustrated with an acidic triazole.
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