Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 15, Pages 1825-1828Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08385h
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Funding
- University of Nottingham
- EPSRC
- Leverhulme Trust
- CONACYT (Mexican Council for Science and Technology) [CVU 600474]
- EPSRC [EP/K038869/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K038869/1] Funding Source: researchfish
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Group 1 salts containing carbazolido NNN pincer ligands are pre-catalysts for the dehydrogenation of Me2NH center dot BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation.
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