Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 19, Pages 2345-2348Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08692j
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Funding
- ANR NANO4FUT and DirectSynBioFuel projects [ANR-16-CE06-0013-01, ANR-15-CE06-0004]
- French National Research Agency
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A shift of selectivity to long chain alpha-olefins has been observed during Fischer-Tropsch synthesis over Co catalysts in the presence of carboxylic acids. The total selectivity to alpha-olefins of 39% was obtained in the presence of acids. The effect has been ascribed to intermediate formation of esters which hinder secondary olefin hydrogenation.
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