4.7 Article

Layer-sliding-driven crystal size and photoluminescence change in a novel SCC-MOF

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 42, Pages 5361-5364

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc01559g

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Funding

  1. National Natural Science Foundation of China [21671175, 21371153]
  2. Program for Science & Technology Innovation Talents in Universities of Henan Province [164100510005]
  3. Zhengzhou University

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A novel silver-chalcogenolate cluster-based framework Ag(12)TPPAAA with long-lived afterglow was successfully synthesized. It transformed into more densely packed Ag(12)TPPAAB and Ag(12)TPPAABC by layer sliding accompanied by macroscopic crystal contraction and changing luminescence.

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