Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 18, Pages 2240-2243Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc09302k
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Funding
- Fonds der Chemischen Industrie
- European Research Council [692640]
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The electron-catalyzed formation of phenanthridines starting from isonitriles initiated by an electrochemical reduction of the Togni reagent is presented. The required number of faradays per mole of starting material and the respective yields clearly show the catalytic character of the electron in this reaction. The mechanism is supported by cyclic voltammetry experiments.
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