Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 45, Pages 5740-5743Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc02758g
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Funding
- National Research Foundation of Korea (NRF) - Korean government (MEST) [2015R1A2A1A10053607]
- Pohang Accelerator Laboratory (PAL) [2017-3rd-2D-008]
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A new double-stranded dinuclear helicate that displays conformational switching in response to temperature was prepared by self-assembly of an aromatic helical foldamer and dichloropalladium(ii). The relative populations of the two helicate conformers, syn-anti and syn-syn, were demonstrated to be reversibly modulated through temperature control.
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