Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 45, Pages 5788-5791Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc03127d
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Funding
- INSPIRE program of the Department of Science and Technology, Government of India [2013/CH-88, IF140686]
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The ability of the -CH functionality in a butylmagnesium cation [Me6TREN-Mg-n-Bu](+) to quantitatively reduce benzophenone has been demonstrated. The hydridic nature of the -CH functionality is highlighted by its abstraction using B(C6F5)(3). -CH abstraction over alkylation in [Me6TREN-Mg-n-Bu](+) is dependent on the nature of the incoming electrophile and the polarity of the solvent.
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