4.7 Article

Pure Ni nanocrystallines anchored on rGO present ultrahigh electrocatalytic activity and stability in methanol oxidation

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 13, Pages 1563-1566

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc09361f

Keywords

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Funding

  1. National Natural Science Foundation of China (NSFC) [51371166, 51571186, 11404338, 51401206, 11504375, 11674321, 11604320]
  2. National Basic Research Program of China [2014CB931704]
  3. Instrument Developing Project of the Chinese Academy of Sciences [YZ201627]
  4. Anhui Provincial Natural Science Foundation [1508085QA21]

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Pure Ni nanoparticles with ultrafine size (2.3 +/- 0.4 nm) embedded on rGO present ultrahigh catalytic activity (1600 mA mg(-1)), excellent stability (1020 mA mg(-1) retained after 1000 cycles), and a saturation concentration (4 M) of methanol for methanol oxidation reactions, which is better than that of all previously reported Ni-based catalysts.

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