4.7 Article

Preparation of a chiral Pt-12 tetrahedral cage and its use in catalytic Michael addition reaction

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 38, Pages 4814-4817

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc01487f

Keywords

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Funding

  1. SERB-India [EMR/2015/002353]
  2. UGC (New Delhi) [201314-NETJRF-10339-74]
  3. Basic Science Research program [2016R1A2B4007433]
  4. Priority Research Centers program through the National Research Foundation of Korea [2009-0093818]

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The reaction of chiral cis-[(1S,2S)-dch] Pt(NO3)(2) (M) [where (1S,2S)-dch = (1S,2S)-1,2-diaminocyclohexane] with a hexadentate ligand (L) in 3 : 1 stoichiometric ratio yielded a [12+4] self-assembled chiral M12L4 molecular tetrahedron (T). The cage T features an internal 3D nanocavity with large open 'windows', enabling it to catalyze Michael addition reactions of a series of nitrostyrene derivatives with indole in a 9 : 1 water : methanol mixture.

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