4.7 Article

An efficient Sm and Ge co-doped ceria nanocomposite electrolyte for low temperature solid oxide fuel cells

Journal

CERAMICS INTERNATIONAL
Volume 44, Issue 1, Pages 170-174

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2017.09.155

Keywords

Electrolyte; Solid oxide fuel cells; Germanium; Nanocomposite; Morphology

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In this study we present a new nanocomposite electrolyte based on samarium (Sm) and germanium (Ge) co doped ceria Ce0.7Sm0.15Ge0.15O2.delta (SGeDC). The nanocomposite electrolyte was prepared using co-precipitation method. The crystal structure and surface morphology were determined using x-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. Four probe dc conductivity indicated the value of 0.074 S/cm at 650 degrees C. The Fuel cell performance was carried out using hydrogen as fuel. The maximum OCV observed was 0.95 V while the peak power density came out to be 600 mW/cm(2) at 600 degrees C. It is suggested that adding Ge, the conductivity as well as performance of this new nanocomposite electrolyte is comparatively enhanced and it can find potential applications in low temperature solid oxide Fuel cells (LTSOFCs).

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