Journal
CERAMICS INTERNATIONAL
Volume 44, Issue 9, Pages 10266-10272Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2018.03.033
Keywords
LT-SOFCs; Perovskite cathode; SrFeTiO3-delta; Material stability; Low polarization resistance; Power density
Categories
Funding
- National Natural Science Foundation of China (NSFC) [11604088]
- NSFC [51772080]
Ask authors/readers for more resources
Stable and compatible cathode materials are a key factor for realizing the low-temperature (LT, <= 600 degrees C) operation and practical implementations of solid oxide fuel cells (SOFCs). In this study, perovskite oxides SrFe1-xTixO3-delta (x < = 0.1), with various ratios of Ti doping, are prepared by a sol-gel method for cathode material for LT-SOFCs. The structure, morphology and thermo-gravimetric characteristics of the resultant SFT powders are investigated. It is found that the Ti is successfully doped into SrFO3-delta to form a single phase cubic perovskite structure and crystal structure of SFT shows better stability than SrFeO3-delta. The dc electrical conductivity and electrochemical properties of SFT are measured and analysed by four-probe and electrochemical impedance spectra (EIS) measurements, respectively. The obtained SFT exhibits a very low polarization resistance (R-p), .01 Omega cm(2) at 600 degrees C. The SFT powders using as cathode in fuel cell devices, exhibit maximum power density of 551 mW cm(-2) with open circuit voltage (OCV) of 1.15 V at 600 degrees C. The good performance of the SFT cathode indicates a high rate of oxygen diffusion through the material at cathode. By enabling operation at low temperatures, SFT cathodes may result in a practical implementation of SOFCs.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available