Journal
CELLULOSE
Volume 25, Issue 8, Pages 4743-4755Publisher
SPRINGER
DOI: 10.1007/s10570-018-1903-3
Keywords
Wood waste; Activated carbon hollow fibers; Supercapacitors; Half-curing; Liquefaction
Funding
- National Natural Science Foundation of China [31270607, 30901133, 51272021, 51142004, 51402010]
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In this paper, several activated carbon hollow fibers (ACHF) with high surface area of similar to 1873 m(2) g(-1) were prepared from wood waste by liquefaction, half-curing and one-step activation methods. Scanning electron microscopy, Nitrogen gas adsorption-desorption and X-ray photoelectron spectroscopy have been used to characterize the morphology, the structure and the composition of ACHF. Results show added wood charcoal had a noticeable influence on the pore structure and electrochemical performance of ACHF. Electrochemical investigation measurements show that ACHF exhibit an outstanding specific capacitance (295 F g(-1) at 0.5 A g(-1)), excellent rate performance (73.8% capacitance retention at 20 A g(-1)), high energy density (7.8 W h kg(-1)) and high capacitance retention of 99.5% over 10,000 charge-discharge cycles. Moreover, the multiple heteroatoms (N, P) from wood liquefaction have a synergistic effect on electrochemical properties of ACHF. These results indicate the present method is promising for the preparation of biomass-derived activated carbon hollow fibers from agricultural and forestry waste in the application of supercapacitors. [GRAPHICS] .
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