Journal
CATALYSIS LETTERS
Volume 148, Issue 9, Pages 2918-2928Publisher
SPRINGER
DOI: 10.1007/s10562-018-2490-5
Keywords
Metal-organic framework; OMS-MIL-100(Fe); Homogeneous catalyst; Aza-Michael reaction
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In the present study, open metal site iron-based MOF [MIL-100(Fe)], by a solvothermal method with polygonal morphology, are synthesised and then applied as a heterogeneous green catalyst for aza-Michael addition of various amines with alpha, beta-unsaturated compounds. The MIL-100(Fe) was found to be efficient, selective, green and heterogeneous catalyst for the aza-Michael reaction. The proposed catalyst has better recyclability and can be reused six times without apparent loss of activity. [GRAPHICS] .
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