Journal
ACTA PHYSICO-CHIMICA SINICA
Volume 32, Issue 1, Pages 61-74Publisher
PEKING UNIV PRESS
DOI: 10.3866/PKU.WHXB201511101
Keywords
Nano-gold catalyst; Platinum-group metal; Green synthesis; Clean reaction; Reductive transformation
Categories
Funding
- National Natural Science Foundation of China [21273044, 21473035]
- China Research Fund for the Doctoral Program of Higher Education, China [2012007000011]
- SINOPEC, China [X514005]
- Science & Technology Commission of Shanghai Municipality, China [08DZ2270500, 12ZR1401500]
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There has been a surge of interest in using supported gold catalysts in green synthesis and clean reactions. Complementary to their traditional platinum-group metal counterparts, catalysis using nano-gold offers a unique opportunity to obtain target products in high yields, control the chemoselectivity, and access more complex organic molecules in a compact, atom- and step-efficient way. Therefore, it has emerged as a hot topic in the field of green catalysis. This review summarizes our research progress in the area of nano-Au catalyzed green reactions and their versatility, application in clean chemical synthesis, especially for the construction of N-containing compounds as well as valorization of biomass-derived feedstocks via gold catalyzed transformations.
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