Journal
9TH INTERNATIONAL CONFERENCE ON MAGNETIC AND SUPERCONDUCTING MATERIALS (MSM15)
Volume 667, Issue -, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/1742-6596/667/1/012008
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The magnetic behavior of Ca3Co4O9 complex shows a very interesting phase transition at high temperature. It is probably that this ordering is due to the spin states of Co3+ and Co4+ ions. It is quite obvious that spin states of Co ions generally change as a function of temperature. We have shown that there is a strong correlation between oxidation states and ligand field parameters during spin state transitions.
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