4.8 Article

Characterization of leaf waste based biochar for cost effective hydrogen sulphide removal from biogas

Journal

BIORESOURCE TECHNOLOGY
Volume 250, Issue -, Pages 635-641

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2017.11.093

Keywords

Leaf waste; Biochar; Biogas; Adsorption; H2S removal

Funding

  1. Department of Science and Technology, Govt. of India [DST/INSPIRE/04/2016/000362]
  2. Department of Biotechnology, Govt. of India
  3. IIT-Delhi

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Installation of decentralized units for biogas production along with indigenous upgradation systems can be an effective approach to meet growing energy demands of the rural population. Therefore, readily available leaf waste was used to prepare biochar at different temperatures and employed for H2S removal from biogas produced via anaerobic digestion plant. It is found that biochar prepared via carbonization of leaf waste at 400 degrees C effectively removes 84.2% H2S (from 1254 ppm to 201 ppm) from raw biogas for 25 min in a continuous adsorption tower. Subsequently, leaf waste biochar compositional, textural and morphological properties before and after H2S adsorption have been analyzed using proximate analysis, CHNS, BET surface area, FTIR, XRD, and SEM-EDX. It is found that BET surface area, pore size, and textural properties of leaf waste biochar plays a crucial role in H2S removal from the biogas.

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