Journal
BIORESOURCE TECHNOLOGY
Volume 251, Issue -, Pages 57-62Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2017.12.022
Keywords
Microwave; Acid; Pretreatment; Lignin; Characteristics; Pyrolysis behaviors
Funding
- National Natural Science Foundation of China [21766019, 21466022]
- International Cooperation Project of MOST. P. R. China [2015DFA60170-4]
- Key Research and Development Program of Jiangxi Province [20171BBF60023]
- Science and Technology Research Project of Jiangxi Province Education Department [GJJ150213]
- Innovation and Entrepreneurship Development Fund of Thousand talents program Talent [1001-02102082]
- Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development [Y707sb1001]
Ask authors/readers for more resources
This study performed microwave-assisted acid pretreatment on pure lignin. The effects of microwave temperature, microwave time, and hydrochloric acid concentration on characteristics and pyrolysis behavior of lignin were examined. Results of ultimate analysis revealed better properties of all pretreated samples than those of raw lignin. Fourier transform infrared spectroscopy analysis showed breakage of beta-O-4 bond and aliphatic side chain, decrease in -OH groups, and formation of C = O groups in pretreatment. Microwave temperature exerted more significant influence on lignin structure. Thermal stability of treated lignin was improved and insensitive to short microwave time and acid concentration under mild conditions. Resulting from improved alkyl-phenols and decreased alkoxy-phenols, microwave-assisted acid pretreatment of lignin yielded bio-oil with excellent quality. Total yield of phenols in pyrolysis vapors (200 degrees C) improved to 14.15%, whereas that of guaiacols decreased to 22.36%. This study shows that microwave-assisted acid pretreatment is a promising technology for lignin conversion.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available