4.6 Article

Precision spectroscopy of the hydrogen molecular ion D2+

Journal

PHYSICAL REVIEW A
Volume 93, Issue 3, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.93.032507

Keywords

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Funding

  1. NSFC [11474316, 11274348]
  2. NSERC of Canada
  3. SHARCnet of Canada
  4. ACEnet of Canada
  5. CAS/SAFEA International Partnership Program

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Expectation values of the Breit operators are calculated for the D-2(+) molecular ion with the vibrational number (nu = 0-4) and angular momentum (L = 0-4). Hyperfine splittings of energy levels of the states (nu = 0-4, L = 3,4) are also determined in the framework of the spin-dependent Breit-Pauli Hamiltonian, which can be considered as an extension of our previous work [ Phys. Rev. A 88, 032519 (2013)]. These theoretical calculations may be used to improve spectroscopic precision of D-2(+) and determine the dissociation or the ionization energy of D-2.

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