4.6 Article

Composite Titanium Silicon Carbide as a Promising Catalyst Support for High-Temperature Proton-Exchange Membrane Fuel Cell Electrodes

Journal

CHEMCATCHEM
Volume 8, Issue 4, Pages 848-854

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201501152

Keywords

composite silicon titanium carbide; high-temperature PEM fuel cells; nanoparticles; platinum; Vulcan carbon

Funding

  1. Seventh Framework Programme through the project CISTEM (FCH-JU Grant) [325262]

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This manuscript focuses on the assessment of a composite titanium silicon carbide (SiCTiC) as a catalyst support for high-temperature proton-exchange membrane fuel cells (HT-PEMFCs). The support showed very high thermal and electrochemical resistances under harsh conditions (phosphoric acid). Pt nanoparticles were successfully deposited on the new SiCTiC support and it demonstrated a higher stability (lower agglomeration of the nanoparticles) than the more conventional Vulcan carbon-based catalyst, both in a commercial formulation and as prepared in the lab, with the same procedure as that used for the novel carbide material under very harsh conditions.

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