Journal
RSC ADVANCES
Volume 6, Issue 21, Pages 17239-17245Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra25424h
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Funding
- Ministry of Science and Technology of China [2013CB834801]
- National Science Foundation of China [21374038, 91233113]
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Two light emitting materials, 9-phenyl-10-(4-(1,2,2-triphenylvinyl) phenyl)-9H-pyreno[4,5-d] imidazole (PyTPEI) and 9-phenyl-10-(4'-(1,2,2-triphenylvinyl)-[1,1'-biphenyl]-4-yl)-9H-pyreno[4,5-d] imidazolepyreneimidazole (PyPTPEI), containing pyrene, imidazole and tetraphenylethene units are synthesized with high yields. Both of them exhibit good thermal stability with decomposition temperatures of 458 degrees C and 474 degrees C, respectively. The fluorescent quantum efficiency in amorphous films are as high as 70% for PyTPEI and 63% for PyPTPEI, respectively. In particular, PyPTPEI shows blue-shifted emission due to the more twisted conformation and reduced intermolecular interactions as compared with PyTPEI. The maximum current efficiency and maximum brightness of a non-doped OLED device using PyTPEI as an active layer reaches 8.73 cd A(-1) and 27 419 cd m(-2), which is better than that of PyPTPEI (7.68 cd A(-1) and 19 419 cd m(-2)).
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