Journal
RSC ADVANCES
Volume 6, Issue 21, Pages 17704-17712Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra02554d
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Funding
- State Key Project of Fundamental Research of Ministry of Science and Technology of the People's Republic of China [2014CB931900, 2012CB932504]
- Chinese Academy of Sciences (Hundred Talents Project)
- China Postdoctoral Science Foundation [119103S240]
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Strongly yellow fluorescent carbon dots (CDs) have been directly synthesized from o-phenylenediamine (o-PD) through a facile microwave-assisted method. The as-prepared o-CDs exhibit excitation-dependent photoluminescent behavior and excellent water-solubility due to some amino or hydroxy functional groups on the surface. An emission peak appears at 573 nm when the o-CDs solution is excited at 400 nm, and the quantum yield (QY) is 38.5%. Owing to their low toxicity and water solubility the as-prepared o-CDs can be directly used for cell imaging. More importantly, the as-prepared o-CDs solution also shows sensitivity for H2O2. The limits of detection (LOD) for Fe3+ and H2O2 are 16.1 nM and 28.1 nM, respectively, which is much lower than what's reported in previous studies. The fluorescence intensity also shows a dependence on pH and the strongest fluorescence intensity appears at pH 9. In addition, we also find that the fluorescent properties of CDs prepared from m-phenylenediamine (m-PDs) and p-phenylenediamine (p-PDs) are quite different from those of o-CDs.
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