Journal
FRONTIERS IN ENERGY RESEARCH
Volume 4, Issue -, Pages -Publisher
FRONTIERS MEDIA SA
DOI: 10.3389/fenrg.2016.00009
Keywords
defects; metal-organic frameworks; methane storage; post-synthetic modification; dangling linker
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Funding
- Agentschap.nl [EOSLT07052]
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Natural gas is increasingly being viewed as one of the most viable alternatives to gasoline. However, its vehicular application will only be widespread if safe and high-capacity methane stores are developed. In this work, we report an over 33% increase in methane uptake on a post-synthetically modified metal-organic framework. The underlying mechanism for this dramatic increase is due to lattice defects formed upon post-synthetic modification. This method may open new approaches to natural gas storage.
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