Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 14, Issue -, Pages 499-505Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.14.35
Keywords
C-C formation; electrochemical oxidative functionalization; n-Bu4NI; redox catalyst
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Funding
- National Natural Science Foundation of China [21472011, 21272021]
- National Key Technology RD Program [2017YFB0307502, 2011BAD23B01]
- Open Project Program of Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University (BTBU)
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An efficient electrocatalytic functionalization of N-arylglycine esters is reported. The protocol proceeds in an undivided cell under constant current conditions employing the simple, cheap and readily available n-Bu4NI as the mediator. In addition, it is demonstrated that the mediated process is superior to the direct electrochemical functionalization.
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