4.7 Review

Recent development of ionic liquid membranes

Journal

GREEN ENERGY & ENVIRONMENT
Volume 1, Issue 1, Pages 43-61

Publisher

KEAI PUBLISHING LTD
DOI: 10.1016/j.gee.2016.05.002

Keywords

Ionic liquid membrane; Supported ionic liquid membrane; Qusai-solidified ionic liquid membrane; Stability; Application

Funding

  1. National Natural Science Foundation of China [21406235, U1407111]
  2. National High Technology Research and Development Program of China [2014AA021006]

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The interest in ionic liquids (IL) is motivated by its unique properties, such as negligible vapor pressure, thermal stability, wide electrochemical stability window, and tunability of properties. ILs have been highlighted as solvents for liquid-liquid extraction and liquid membrane separation. To further expand its application in separation field, the ionic liquid membranes (ILMs) and its separation technology have been proposed and developed rapidly. This paper is to give a comprehensive overview on the recent applications of ILMs for the separation of various compounds, including organic compounds, mixed gases, and metal ions. Firstly, ILMs was classified into supported ionic liquid membranes (SILMs) and quasi-solidified ionic liquid membranes (QSILMs) according to the immobilization method of ILs. Then, preparation methods of ILMs, membrane stability as well as applications of ILMs in the separation of various mixtures were reviewed. Followed this, transport mechanisms of gaseous mixtures and organic compounds were elucidated in order to better understand the separation process of ILMs. This tutorial review intends to not only offer an overview on the development of ILMs but also provide a guide for ILMs preparations and applications. (C) 2016, Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd.

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