Binding energies and structures of two-dimensional excitonic complexes in transition metal dichalcogenides

The stochastic variational method is applied to excitonic formations within semiconducting transition metal dichalcogenides using a correlated Gaussian basis. The energy and structure of two- to six-particle systems are investigated along with their dependence on the effective screening length of the two-dimensional Keldysh potential and the electron-hole effective mass ratio. Excited state biexcitons are shown to be bound, with binding energies of the L = 0 state showing good agreement with experimental measurements of biexciton binding energies. Ground and newly discussed excited state exciton-trions are predicted to be bound and their structures are investigated.