Journal
CHEMCATCHEM
Volume 8, Issue 6, Pages 1033-1037Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201501309
Keywords
green chemistry; methylenecyclopropanes; selectivity control; selenium; small ring systems
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Funding
- National Natural Science Foundation of China (NNSFC) [21202141, 21173182]
- Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions
- Yangzhou Nature Science Foundation [YZ2014040]
- Opening Foundation of the Key Laboratory of Environmental Materials and Engineering of Jiangsu Province [K14010]
- Open Project Program of Jiangsu Key Laboratory of Zoonosis [R1509]
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Catalyst screening and optimization of reaction conditions allowed control of the organoselenium-catalyzed oxidative ring expansion of highly active methylenecyclopropanes to give substituted cyclobutanones selectively. This protocol employs H2O2 as a clean oxidant and generates no waste and, therefore, provides green access to useful, but not readily available, substituted cyclobutanones under mild conditions.
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