4.6 Article

Dinuclear zinc-catalyzed desymmetric intramolecular aldolization: an enantioselective construction of spiro[cyclohexanone-oxindole] derivatives

Journal

RSC ADVANCES
Volume 6, Issue 36, Pages 30683-30689

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra02296k

Keywords

-

Funding

  1. National Natural Science Foundation of China [21272166, 21572150]
  2. Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions [13KJA150004]
  3. Program for New Century Excellent Talents in University [NCET-12-0743]
  4. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
  5. Scientific and Technologic Infrastructure of Suzhou [SZS201207]

Ask authors/readers for more resources

Based on oxindole-derived diketones as the substrates, asymmetric desymmetrizing intramolecular aldol or aldol condensation reactions are reported, which are catalyzed by a Trost bis-ProPhenol dinuclear zinc complex. The corresponding spiro[cyclohexanone-oxindole] derivatives were obtained in good yields with moderate to good enantioselectivities.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available