Journal
APPLIED SURFACE SCIENCE
Volume 457, Issue -, Pages 752-763Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2018.06.135
Keywords
Aniline trimer; Electrodeposition; Corrosion protection; Super-hydrophobic; Passivation film
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Funding
- National Key R&D Program of China [2016YFE0203600]
- Chinese Academy of Sciences [XDA13040601, Y60707WR04]
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Novel super-hydrophobic aniline trimer-containing siliceous coatings were carefully acquired through electrodeposition in a mixed solution of tetraethoxysilane and triethoxysilylpropyl isocyanate modified aniline trimer (M-AT). Chemical constitution, morphology, hydrophobicity and anticorrosion ability of as-prepared hybrid coatings were investigated by corresponding equipment. Compared to pure silica coating, the AT-containing silica coatings presented excellent super-hydrophobicity and enhanced anticorrosion performance. The impedance was the highest and the corrosion current density was the lowest for modified silica coating with proper M-AT (5 wt%). The super-hydrophobic of AT-containing silica coating was conducive to avoid the direct contact between corrosion medium and metal substrate. The peculiar oxidation-reduction feature of AT was help to promote the generation of passivation films (ferric oxide and ferroferric oxide). The combined action of above-mentioned two functions facilitated the perfection of corrosion performance for AT-containing silica coating.
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