4.7 Article

Hierarchical flower-like SnS grafted with glucosamine-derived nitrogen-doped carbon with enhanced reversible Li-storage performance

Journal

APPLIED SURFACE SCIENCE
Volume 458, Issue -, Pages 86-94

Publisher

ELSEVIER
DOI: 10.1016/j.apsusc.2018.07.082

Keywords

Tin sulfides; N-doped carbon; Nanocomosites; Anode; Li-ion battery

Funding

  1. Guangdong Natural Science Foundation [2017A030313074, 2016A030313667]
  2. Science and Technology Planning Project of Guangdong Province [2014A010106032]
  3. Natural Science Foundation of Lingnan Normal University [LZL1801]

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A simple hydrothermal plus annealing method has been developed to fabricate SnS/NC nanocomposites and their electrochemcial Li-storage performance has also been investigated. The as-prepared composites are characterized by XRD, SEM, EDS, Raman, BET and XPS. In this composite, ultrathin SnS nanosheets are well hybridized with glucosamine-derived nitrogen-doped carbon to form hierarchical porous architectures with large surface areas. Benefiting from the desirable structural merits as well as the generated synergism between components, the SnS/NC composite electrode delivers an enormously enhanced electrochemical lithium-storage performance including large reversible capacity of 832 mAhg(-1) after 100 cycles, enhanced cyclability and superior high-rate capability.

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