Journal
APPLIED SURFACE SCIENCE
Volume 430, Issue -, Pages 424-437Publisher
ELSEVIER
DOI: 10.1016/j.apsusc.2017.07.056
Keywords
TiO2; WS2; Photocatalysis; {101} and {001} facets; Heterojunction
Categories
Funding
- Chinese National Natural Science Foundation [51602086, 61072015]
- Zhejiang Provincial Natural Science Foundation of China [LY16E020007]
- Zhejiang Xinmiao Talents Program [2016R407034]
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The present study focuses on anatase TiO2 with various crystal facets, such as {101} and {001} combined with two-dimensional (2D) WS2 nanolayers to form a heterojunction and the related photocatalytic activity. The {101} facets of anatase TiO2 is superior in the compositing of WS2; the composite shows a 90% enhancement compared with pristine TiO2 than the composited WS2 on the {001} facets which only boosted 7%. However, in our previous study, anatase TiO2 with coexposed {101} and {001} facets demonstrated great improvement in photocatalytic activity in the composited MoS2. Results reveal that when anatase TiO2 with coexposed {101} and {001} facets are composited with 2D transition metal sulfide (MoS2 and WS2), dual heterojunction will form. Some {101} facets are co-exposed with {001} facets, and this co-exposure will construct a crystal facet heterojunction. Moreover, a semiconductor heterojunction exists between TiO2 and MoS2 or WS2. This dual heterojunction is found to have a synergistic effect. It is revealed that the position of energy band plays a decision role in the dual heterojunction. This finding offers a deeper understanding in the construction of heterojunction on different crystal facets. (C) 2017 Elsevier B.V. All rights reserved.
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