High performance Bi0.5Na0.5TiO3-BiAlO3-K0.5Na0.5NbO3 lead-free pyroelectric ceramics for thermal detectors

Both high pyroelectric properties and good temperature stability of ferroelectric materials are desirable when used for applications in infrared thermal detectors. In this work, we report leadfree ternary 0.97(0.99Bi(0.5)Na(0.5)TiO(3)-0.01BiAlO(3))-0.03K(0.5)Na(0.5)NbO(3) (BNT-BA-KNN) ceramics, which not only exhibits a large pyroelectric coefficient (p similar to 3.7 x 10(-8) C cm(-2) K-1) and figures of merit (F-i, F-v, and F-d) but also shows excellent thermal stable properties. At room temperature, F-i, F-v, and F-d are determined as high as 1.32 x 10(-10) m/V, 2.89 x 10(-2) m(2)/C, and 1.15 x 10(-5) Pa-1/2 at 1 kHz and 1.32 x 10(-10) m/V, 2.70 x 10(-2) m(2)/C, and 1.09 x 10(-5) Pa-1/2 at 20 Hz, respectively. During the temperature range of RT to 85 degrees C, the achieved p, F-i, F-v, and F-d do not vary too much. The high depolarization temperature and the undispersed ferroelectric-ergodic relaxor phase transition with a sharp pyroelectric coefficient peak value of similar to 400 x 10(-8) C cm(-2) K-1 are suggested to be responsible for this thermal stability, which ensures reliable actual operation. The results reveal the BNT-BA-KNN ceramics as promising lead-free candidates for infrared thermal detector applications. Published by AIP Publishing.