Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 32, Issue 4, Pages -Publisher
WILEY
DOI: 10.1002/aoc.4273
Keywords
click reaction; direct amination; heterogenous catalyst; nickel nanoparticle
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Funding
- Isfahan University of Technology (IUT), IR of Iran
- Isfahan Science and Technology Town (ISTT), IR of Iran
- Center of Excellence in Sensor and Green Chemistry Research (IUT)
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A practical method for the direct amination of phenols using 2,4,6-trichloro-1,3,5-triazine (TCT) as an efficient promotor for the activation of phenols in the presence of an efficient and recyclable heterogeneous catalyst prepared by immobilization of nickel particles on triazole modified chitosan is described. This heterogeneous catalyst has demonstrated a promising activity for the conversion of phenolic compounds to their corresponding amine under mild conditions. Moreover, the obtained catalyst can be reused in five consecutive runs with consistent catalytic activity.
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