Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 32, Issue 6, Pages -Publisher
WILEY
DOI: 10.1002/aoc.4331
Keywords
adsorption isotherm and kinetics; Fe3O4@TiO2 nanoparticles; Fe3O4@TiO2-methyltrimethoxysilane nanocomposite; methylene blue dye
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Funding
- Universiti Teknologi Malaysia Research University Grant (Professional Development UTM) [RJ130000.7113.4N005]
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Novel magnetic titanium dioxide nanoparticles decorated with methyltrimethoxysilane (Fe3O4@TiO2-MTMOS) were successfully fabricated via a sol-gel method at room temperature. The synthesized material was characterized using Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, thermogravimetric analysis and vibrating sample magnetometry. The removal efficiency of the adsorbent was evaluated through the adsorption of methylene blue (MB) dye from water samples. The adsorption isotherm and kinetics were evaluated using various models. The Langmuir model indicated a high adsorption capacity (11.5mgg(-1)) of Fe3O4@TiO2-MTMOS. The nanocomposite exhibited high removal efficiency (96%) and good regeneration (10 times) compared to Fe3O4 and Fe3O4@TiO2 at pH = 9.0. Based on the adsorption mechanism, electrostatic interaction plays a main role in adsorption since MB dye is cationic in nature at pH = 9, whereas the adsorbent acquired an anionic nature. The newly synthesized Fe3O4@TiO2-MTMOS can be used as a promising material for efficient removal of MB dye from aqueous media.
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