4.8 Article

Synergetic effect of carbon sphere derived from yeast with magnetism and cobalt oxide nanochains towards improving photodegradation activity for various pollutants

Journal

APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 220, Issue -, Pages 137-147

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2017.08.037

Keywords

Yeast; Pe(3)O(4)@C; Cobalt oxides; Universal photocatalytic activity; Visible light

Funding

  1. National Natural Science Foundation of China [21407059, 21407064, 21606114]
  2. Natural Science Foundation of Jiangsu Province [BK20140527, BK20140532, BK20150536]
  3. Postdoctoral Science Foundation of Jiangsu Province [1501102B]

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Developing high-efficiency and low-cost semiconductor photocatalysts with carbon layer modification has been proved to possess the potential advantage for dramatically improved photocatalytic performance in recent years. Here, a novel magnetic core-shell Fe3O4@C modified with Co3O4 nanochains photocatalyst (Fe3O4@C/Co3O4) is first constructed via a facile synthetic strategy using inexpensive and ordinary yeast as carbon source. The obtained composite structure is conducive to the transfer and separation of charge carriers due to the synergetic effect of carbon layer and Co3O4 nanochains. In consequence, the photodegradation activity of various pollutants is significantly enhanced relative to that of pure Co3O4 under visible light irradiation. Moreover, the introduction of magnetic materials makes this photocatalyst recycled easily by an external magnetic field and reused effectively without obvious activity loss. This work may provide a feasibility analysis and exemplificative strategy for using simple raw materials as carbon source to observably improve universal photocatalytic activity of composite semiconductor photocatalyst.

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