4.8 Article

CuInS2 sensitized TiO2 hybrid nanofibers for improved photocatalytic CO2 reduction

Journal

APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 230, Issue -, Pages 194-202

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2018.02.042

Keywords

TiO2 Nanofiber; CuInS2 nanoplates; Direct Z-scheme heterojunction; Photocatalytic CO2 reduction

Funding

  1. NSFC [51320105001, 21573170, U1705251, 21433007]
  2. NSFHP [2015CFA001]
  3. Innovative Research Funds of SKLWUT [2017-ZD-4]
  4. Australian Research Council [DE160101488]
  5. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing (Wuhan University of Technology) [2018-KF-17]
  6. Australian Research Council [DE160101488] Funding Source: Australian Research Council

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Photocatalytic CO2 reduction into solar fuels over photocatalysts has theoretically and practically become a hot research topic. Herein, we fabricated a novel hybrid TiO2 nanofiber coated by CuInS2 nanoplates through a hydrothermal method. The materials were characterized by X-ray diffraction, electron microscopes, UV-vis absorption spectra, nitrogen sorption, X-ray photoelectron spectroscopy and electrochemical impudence spectroscopy. The resulting TiO2/CuInS2 hybrid nanofibers exhibit superior photocatalytic activity for CO2 reduction under irradiation, due to the generation of direct Z-scheme heterojunction between TiO2 and CuInS2. This work may provide an alternate methodology to design and fabricate multicomponent TiO2-based photocatalyst for high-efficiency CO2 photoreduction.

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