Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 224, Issue -, Pages 214-221Publisher
ELSEVIER
DOI: 10.1016/j.apcatb.2017.10.022
Keywords
Dry reforming of methane; Ce substitution; Perovskite; CeO2
Funding
- National Natural Science Foundation of China [21427804]
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Effects of Ce substitution at the A-site of LaNi0.5Fe0.5O3 perovskite on the enhanced catalytic activity for dry reforming of methane (DRIVI) were studied. La1-xCexNi0.5Fe0.5O3 mixed-oxide catalyst precursors were synthesized by a sol-gel self-combustion method. The CH4 and CO2 conversions increase for the samples with x = 0.4-0.6. The used catalysts consist of Ni, CeO2, and (LaCe)(NiFe)O-3. The metallic Ni phase provides the primary catalytic activity, while (LaCe)(NiFe)O-3 perovskite dominates the enhanced catalytic activity. It is confirmed that the solubility of Ce in the perovskite is high under the DRM conditions. Our results suggest that the Ce3+ cation at the A-site of (LaCe)(NiFe)O-3 is active for DRM, and the relevant mechanisms are discussed.
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