Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 237, Issue -, Pages 251-262Publisher
ELSEVIER
DOI: 10.1016/j.apcatb.2018.05.093
Keywords
Fe2O3; Ag/CeO2; Soot oxidation catalyst; Crystal plane; Tandem oxygen delivery
Funding
- National Natural Science Foundation of China [51702304]
- Natural Science Foundation of Shandong Province [ZR2017BEM006]
- Postdoctoral Science Foundation of Shandong Province [201601009]
- China Science and Technology Exchange Center [2016YFE0126600]
- National Key R&D Program of China [2017YFC0211102, 2017YFC0211202]
- China Postdoctoral Science Foundation [2015M580607, 2017T100516]
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In this work, model alpha-Fe2O3 catalysts with different morphologies were synthesized to investigate crystal plane effects on soot oxidation. The results revealed that the electron-rich state of Fe2O3 {113} planes conferred them more surface O-x(-) and thus better catalytic performance than the {014} and {012} planes. Surface grafting of a polycrystalline CeO2 layer onto Fe2O3 gave rise to Fe2O3@CeO2 catalysts with drastically increased oxygen utilization. More importantly, by loading Ag nano-particles on the surface of Fe2O3@CeO2, a tandem oxygen delivery route was opened, resulting in strong O-x(-) generation/regeneration ability and superior low temperature soot oxidation activity. These Ag/Fe2O3@CeO2 catalysts overwhelmed the nano-cubic Ag/CeO2 in both catalyst cost and activity, making them very promising for application in catalyzed gasoline particulate filters (CGPFs).
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