3.9 Review

Calibration and correction of LA-ICP-MS and LA-MC-ICP-MS analyses for element contents and isotopic ratios

Journal

SOLID EARTH SCIENCES
Volume 1, Issue 1, Pages 5-27

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.sesci.2016.04.002

Keywords

LA-ICP-MS; LA-MC-ICP-MS; Calibration and correction method; Elemental composition; Isotopic composition; Geological samples

Funding

  1. National Natural Science Foundation of China [41125013, 41525012]
  2. Ministry of Education [B07039]
  3. MOST of State Key Laboratory of Geological Processes and Mineral Resources [MSFGPMR04]

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LA-ICP-MS and LA-MC-ICP-MS have been the techniques of choice for achieving accurate and precise element content and isotopic ratio, the state-of-the-art technique combines the advantages of low detection limits with high spatial resolution, however, the analysis accuracy and precision are restricted by many factors, such as sensitivity drift, elemental/isotopic fractionation, matrix effects, interferences and the lack of sufficiently matrix-matched reference materials. Thus, rigorous and suitable calibration and correction methods are needed to obtain quantitative data. This review systematically summarized and evaluated the interference correction, quantitative calculation and sensitivity correction strategies in order to provide the analysts with suitable calibration and correction strategies according to the sample types and the analyzed elements. The functions and features of data reduction software ICPMSDataCal were also outlined, which can provide real-time and on-line data reduction of element content and isotopic ratios analyzed by LA-ICP-MS and LA-MC-ICP-MS. Copyright (C) 2016, Guangzhou Institute of Geochemistry. Production and hosting by Elsevier B.V.

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