Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 34, Pages 10966-10970Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201806502
Keywords
adsorption; colloidal zeolites; inorganic chemistry; monolayers; thin films
Categories
Funding
- Swedish Energy Agency
- Swedish Research Council for Environment, Agricultural Sciences and Spatial Planning FORMAS
- Bio4Energy
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We report novel routes for synthesis of defect-free, hydrophobic and monodispersed 10 nm (5 unit cells) thick MFI crystals and 100 nm CHA crystals. The crystals are obtained in high yield and display very high 1-butanol adsorption from aqueous solution. These crystals are assembled in monolayers for the growth of ultrathin and uniformly oriented films with thicknesses of 36 nm and 330 nm, respectively, using a synthesis gel in the form of a powder. This method is very simple and may open up for industrial preparation of materials with improved performances.
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