Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 6, Pages 1712-1716Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201712019
Keywords
C-H activation; cycloisomerization; cyclopropene; furans; rhodium(III) catalysis
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Funding
- Alexander von Humboldt Foundation
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A novel and efficient strategy for the synthesis of arylated furans was successfully developed by a Rh-III-catalyzed coupling of N-phenoxyacetamides and cyclopropenyl esters. Mechanistic investigation reveals that the arylated furans are formed via arylation of the cyclopropenyl esters followed by cycloisomerization.
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