Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 11, Pages 2934-2937Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201712347
Keywords
block copolymers; cobalt; one pot synthesis; organometallic-mediated radical polymerization; vinylidene fluoride
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Funding
- French national agency (ANR grant FLUPOL)
- FNRS
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An unprecedented level of control for the radical polymerization of vinylidene fluoride (VDF), yielding well-defined PVDF (at least up to 14500 g mol(-1)) with low dispersity (<= 1.32), was achieved using organometallic-mediated radical polymerization (OMRP) with an organocobalt compound as initiator. The high chain-end fidelity was demonstrated by the synthesis of PVDF-and PVAc-containing di-and triblock copolymers. DFT calculations rationalize the efficient reactivation of both head and tail chain end dormant species.
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