Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 30, Pages 9543-9547Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201805728
Keywords
azaacenes; bromination; n-channel semiconductors; radical anions; thin-film transistors
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Funding
- Deutsche Forschungsgemeinschaft [SFB 1249, GRK 2112]
- Julius-Maximilians-Universitat Wurzburg
- Chinese Scholarship Council [201406170060]
- Bavarian State Ministry of Science, Research, and the Arts (Collaborative Research Network Solar Technologies Go Hybrid)
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A cyclocondensation of TIPS-ethynyl-substituted diaminoarenes with in situ obtained 4,5-dibromocyclohexa-3,5-diene-1,2-dione has led to the synthesis of tetrabromotetraazapentacene (BrTAP). BrTAP is easily reduced to its air-stable radical anion and electron mobilities > 0.56 cm(2) V-1 s(-1) can be achieved in thin-film transistors.
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