Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 32, Pages 10333-10337Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201805118
Keywords
alkenes; allylic compounds; C-H activation; nickel; photocatalysis
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Funding
- European Research Council under the European Union [617044]
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An efficient protocol for the direct allylic C(sp(3))-H bond activation of unactivated tri- and tetrasubstituted alkenes and their functionalization with aryl- and vinylbromides by nickel and visible-light photocatalysis has been developed. The method allows C(sp(2))-C(sp(3)) formation under mild reaction conditions with good functional-group tolerance and excellent regioselectivity.
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