Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 6, Pages 1543-1546Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201710707
Keywords
amination; carbometalation; cyclopropanols; cyclopropylamines; oxidation
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Funding
- European Research Council under the Seventh Framework Program of the European Community (ERC Grant) [338912]
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The catalytic asymmetric carbometalation of cyclopropenes followed by either an electrophilic oxidation or amination reaction provides a unique approach to the formation of diastereomerically pure and enantiomerically enriched cyclopropanol and cyclopropylamine derivatives, respectively.
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