Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 16, Pages 4234-4241Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201710330
Keywords
amination; catalysis; C-H bond functionalization; oxidation; regioselectivity
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Funding
- Department of NIH [GM-58108, GM 11581201]
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Direct functionalization of natural products is important for studying the structure-activity and structure-property relationships of these molecules. Recent advances in the transition-metal-catalyzed functionalization of C(sp(3))-H bonds, the most abundant yet inert bonds in natural products, have allowed natural product derivatives to be created selectively. Strategies to achieve such transformation are reviewed.
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