Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 19, Pages 5463-5466Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201711846
Keywords
gold; luminescence; organic light-emitting devices; thin films
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Funding
- University of Hong Kong
- URC Strategically Oriented Research Theme on Functional Materials for Molecular Electronics Towards Materials and Energy Applications
- University Grants Committee (UGC) Areas of Excellence Scheme (AoE) of the Hong Kong Special Administrative Region, China [AoE/P-03/08]
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A new class of fused heterocyclic tridentate ligand-containing alkynylgold(III) complexes with tunable emission color has been successfully designed and synthesized. Structural modification of the sigma-donating fused heterocyclic alkynyl ligands, including substituted fluorene, carbazole, and triphenylamine, enables a large spectral shift of about 110nm (ca.3310cm(-1)) that covers the green to red region to be realized with the same tridentate ligand-containing alkynylgold(III) complexes in solid-state thin films. Interestingly, the energy of the excimeric emission can be controlled by the rational design of the fused heterocyclic alkynyl ligands. Superior solution-processable organic light-emitting devices (OLEDs) with high external quantum efficiencies (EQEs) of 12.2, 13.5, 9.3, and 5.2% were obtained with green, yellow, orange, and red emission. These high EQE values are comparable to those of the vacuum-deposited OLEDs based on structurally related alkynylgold(III) complexes.
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