Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 14, Pages 3682-3686Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201713324
Keywords
asymmetric catalysis; boronic acids; carbometalation; cyclopropanes; rhodium
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Funding
- European Research Council [338912]
- European Research Council (ERC) [338912] Funding Source: European Research Council (ERC)
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A variety of highly diastereo- and enantiomerically enriched arylcyclopropanes is obtained through the asymmetric rhodium-catalyzed arylation reaction of achiral nonfunctionalized cyclopropene derivatives with commercially available aryl boronic acids in the presence of (R,S)-Josiphos.
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