Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 23, Pages 6819-6824Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201801369
Keywords
aerogel networks; copper; electrocatalysts; mimicking peroxidases; nanoassembly
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Funding
- National Natural Science Foundation of China [21675084, 21575004]
- creative research group of bioanalytical chemistry of Anhui Province
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A facile strategy is presented to form 3D porous Cu@Cu2O aerogel networks by self-assembling Cu@Cu2O nanoparticles with the diameters of ca. 40 nm for constructing catalytic interfaces. Unexpectedly, the prepared Cu@Cu2O aerogel networks display excellent electrocatalytic activity to glucose oxidation at a low onset potential of ca. 0.25 V. Moreover, the Cu@Cu2O aerogels also can act as mimicking-enzymes including horseradish peroxidase and NADH peroxidase, and show obvious enzymatic catalytic activities to the oxidation of dopamine (DA), o-phenyldiamine (OPD), 3,3,5,5-tetramethylbenzidine (TMB), and dihydronicotinamide adenine dinucleotide (NADH) in the presence of H2O2. These 3D Cu@Cu2O aerogel networks are a new class of porous catalytic materials as mimic peroxidases and electro-catalysts and offer a novel platform to construct catalytic interfaces for promising applications in electrochemical sensors and artificial enzymatic catalytic systems.
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